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Department of Chemistry
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Liu, Rai-Shung
Title: Professor & Dean, College of Science    Chinese Version

Education:

Columbia University(USA)(Ph.D) (1981)
National Tsing Hua University(B.S.) (1976)

Office: Chemistry Building R509
Phone number: 33385
E-mail: rsliu@mx.nthu.edu.tw
Web site: http://my.nthu.edu.tw/~chem/faculty/e-rsliu_web/e-rslweb.html

Professional Experience:

1987 ~
1983 ~ 1987
1981 ~ 1982

 

Professor of NTHU
Associate Professor of NTHU
Postdoctoral Research,
Texas A&M University - College Station

Research Interest:

Organic, Organometallics and Inorganic


Publications:(After 2010)


  1. Gold-catalyzed Stereocontrolled Oxacyclization/[4+2]-Cycloaddition Cascade of Ketone-allene Substrates. Teng Tse-Min and Rai-Shung Liu,* J. Am. Chem. Soc. 2010, 132, 9298.
     
  2. Gold-catalyzed Stereoselective Synthesis of 9-Oxabicyclo[3.3.1]nona-4,7-dienes from Diverse 1-Oxo-4-oxy-5-ynes: A Viable Formal [4+2]-Cycloaddition on s-trans-Heterodiene Framework. Tse-Min Teng, Arindam Das, Deepak B. Huple and Rai-Shung Liu,* J. Am. Chem. Soc. 2010, 132, 12565.
     
  3. Gold-catalyzed Oxidative Ring Expansions and Cleavages of Alkynylcyclopropanes via Intermolecular Ph2SO-oxidation Reactions. Chia-Wen Li, Kamalkishore Pati, Guan-You Lin, Shariar Md. Abu Sohel, Hsiao-Hua Hung, and Rai-Shung Liu* Angew. Chem. Int. Ed. 2010, 49, 9891.
     
  4. Gold-catalyzed Stereoselective Synthesis of Azacyclic Compounds through a Redox/[2+2+1]-Cycloaddition Cascade of Nitro-alkyne Substrates. Appaso M. Jadhav, Sabyasachi Bhunia, Hsin-Yi Liao and Rai-Shung Liu,* J. Am. Chem. Soc. 2011, 133, 1769–1771.
     
  5. Gold-catalyzed Oxidative Cyclization of 1,5-Enynes Using External Oxidants. Dhananjayan Vasu, Hsiao-Hua Hung, Sabyasachi Bhunia, Sagar Ashok Gawade, Arindam Das and Rai-Shung Liu* Angew. Chem. Int. Ed. 2011, 50, 6911.
     
  6. Gold-Catalyzed 1,2-Difunctionalizations of Aminoalkynes Using only N- and O-Containing Oxidants. Anupam Mukherjee, Ramesh B. Dateer, Rupsha Chaudhuri, Sabyasachi Bhunia, Somnath Narayan Karad and Rai-Shung Liu*, J. Am. Chem. Soc. 2011, 133, 15372.
     
  7. Gold-Catalyzed Formal [3+3] and [4+2]-Cycloaddition Reactions of Nitrosobenzenes with Alkenylgold Carbenoids. Vinayak Vishnu Pagar, Appaso Mahadev Jadhav and Rai-Shung Liu* J. Am. Chem. Soc. 2011, 133, 20728.
     
  8. Gold-Catalyzed Intermolecular [4+2]- and [2+2+2]-Cycloadditions of Ynamides with Alkenes, Ramesh B. Dateer, Balagopal S. Shaibu and Rai-Shung Liu,* Angew. Chem. Int. Ed. 2012, 51, 113 (selected as a hot paper).
     
  9. Gold-Catalyzed Oxidative Cyclizations of cis-3-En-1-ynes to form Cyclopentenone Derivatives. Sabyasachi Bhunia, Satish Ghorpade, Deepak B. Huple and Rai-Shung Liu,* Angew. Chem. Int. Ed. 2012, 51, 2939.
     
  10. Intermolecular Gold-Catalyzed Diastereo- and Enantioselective [2+2+3]-Cycloadditions of 1,6-Enynes with Nitrones. Sagar Ashok Gawade, Sabyasachi Bhunia and Rai-Shung Liu*, Angew. Chem. Int. Ed. 2012, 51, 7835-38.
     
  11. Retention of Stereochemistry in Gold-Catalyzed [4+3]-Cycloaddition of Epoxides with Arenynamides. Somnath Narayan Karad, Sabyasachi Bhunia and Rai-Shung Liu*, Angew. Chem. Int. Ed. 2012, 51, 8722 (selected as a hot and frontispiece paper).
     
  12. Development of Povarov Reaction/Carbene Generation Sequence on Alkenyldiazocarbonyl Compounds. Appaso Mahadev Jadhav, Vinayak Vishnu Pagar and Rai-Shung Liu*, Angew. Chem. Int. Ed. 2012, 51, 11809.
     
  13. Gold-Catalyzed Oxidative Cyclizations on 1,4-Enynes: Evidence for a g-Substituent Effect on Wagner-Meerwein Rearrangement. Satish Ghorpade, Ming-Der Su* and Rai-Shung Liu*, Angew. Chem. Int. Ed. 2013, 52, 4229-4234
     
  14. Gold-catalyzed Cyclization/Oxidative [3+2]-Cycloadditions of 1,5-Enynes with Nitrosobenzenes without Additional Oxidants. Chun-Hao Chen, Yen-Ching Tsai and Rai-Shung Liu*. Angew, Chem. Int. Ed. 2013, 52, 4599-4603.
     
  15. Gold-Catalyzed Formal Cycloadditions of 2-Ethynylbenzyl Ethers with Organic Oxides or a-Diazo Esters. Samir Kundlik Pawar, Chiou-Dong Wang, Sabyasachi Bhunia, Appaso Mahadev Jadhav and Rai-Shung Liu,* Angew, Chem. Int. Ed. 2013, 52, 7559.
     
  16. Zn(II)- or Ag(I)-catalyzed 1,4-Metathesis Reactions Between 3-En-1-Ynamides and Nitrosoarenes. Sagar Ashok Gawade, Deepak. B. Huple, and Rai-Shung Liu*, J. Am. Chem. Soc. 2014, 136, 2978-2981.
     
  17. Gold-Catalyzed 1,2-Oxoarylations of Nitriles with Pyridine-Derived Oxides. Somnath Narayan Karad and Rai-Shung Liu*, Angew. Chem. Int. Ed. 2014, 53, 5444-5448.
     
  18. Gold-catalyzed Regiocontrolled [2+2+2]-Cycloadditions of Ynamides with Two Discrete Nitriles to Construct 4-Aminopyrimidine Cores. Somnath Narayan Karad and Rai-Shung Liu*, Angew. Chem. Int. Ed. 2014, 53, 9072-9076.
     
  19. Copper-Catalyzed Oxidatively Dimeric Cyclizations of 3-N-Hydroxyaminoprop-1-enes to form 1,4-Dihydroxy-2,3-diaminocyclohexanes of C2-symmetry. Satish Ghorpade and Rai-Shung Liu*, Angew. Chem. Int. Ed. 2014, 53, in press.

 

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